Cite this article as:
Smotrov M. P. Phase Equilibria and Critical Phenomena in the Water–i-Butyric Acid Binary System. Izvestiya of Saratov University. Chemistry. Biology. Ecology, 2016, vol. 16, iss. 1, pp. 21-24. DOI: https://doi.org/10.18500/1816-9775-2016-16-1-21-24
Phase Equilibria and Critical Phenomena in the Water–i-Butyric Acid Binary System
Phase equilibria and critical phenomena in the water-i-butyric acid binary system were studied by the visual polythermal method over the temperature range –10–30°C. The system is characterized by delamination with an upper critical solution temperature (UCST) equal 25.8°C. In the system at –1.8°C, these occurs a nonvariant monotectic equilibrium whose solid phase are ice crystals. The phase diagram of the system is plotted.
1. Химическая энциклопедия / гл. ред. И. Л. Кнунянц : в 5 т. М. : Сов. энцикл., 1988–1998.
2. Greer S. C. Coexistence curves at liquid-liquid critical points : Ising exponents and extended scaling // Phys. Rev. 1976. Vol. 14, № 5. P. 1770–1780.
3. Pojman J. A., Whitmore C., Liveri M. L., Lombardo R. Evidence for the Existence of an Effective Interfacial Tension between Miscible Fluids : Isobutyric Acid-Water and 1-Butanol-Water in a Spinning-Drop Tensiometer // Langmuir. 2006. Vol. 22. P. 2569–2577.
4. Cherif E., Bouanz M. Density, viscosity and electrical conductivity of isobutyric acid–water with added ions in the critical regions // Phys. and Chem. of Liq. 2009. Vol. 47, № 6. P. 626–637.
5. Cherif E., Bouanz M. Electrical Conductivity along Phase Diagram of the Critical Mixture Isobutyric Acid – Water with Added (K+, Cl-) Ions // Intern. J. of Mol. Sci. 2003. Vol. 4. P. 326–334.
6. Аносов В. Я., Озерова М. И., Фиалков Ю. Я. Основы физико-химического анализа. М. : Наука, 1976. 504 с.
7. Трейбал Р. Жидкостная экстракция / пер. с англ. ; под ред. С. З. Кагана. М. : Химия, 1966. 724 с.
8. Самойлов О. Я. Структура водных растворов электролитов и гидратация ионов. М. ; Л. : Изд-во АН СССР, 1957. 182 с.
9. Крестов Г. А. Термодинамика ионных процессов в растворах. Л. : Химия. Ленингр. отд-ние, 1984. 272 с.