сорбция

Glauconite as a sorbent of 4-nitrophenol

The sorption properties of glauconite from Beloozersk deposits (Saratov region) for 4-nitrophenol (4-NF) have been investigated. The effect of glauconite on pH and 4-nitrophenol structure in solution is estimated. It is shown that glauconite increases pH of aqueous environment to 8 and shifts the equilibrium towards the formation of aci-form 4-NF. The conditions of sorption 4-NF by glauconite are established: the sorption time 20 min, the mass of the sorbent (0.50–1.0) g.

Antibacterial properties of a biologically active composite based on glauconite

Glauconite, a natural aluminosilicate, exhibits good sorption properties, is an affordable, cheap material, and has the prospect of being used in construction, ecology, medicine, cosmetology, animal husbandry, poultry farming, agriculture, etc. An urgent task is to study the sorption activity of glauconite in the Beloozersky deposit in the Saratov region in relation to biologically active substances for the creation of antimicrobial composites. The elemental composition and surface morphology of glauconite grains are determined.

Adsorption of organic reagents by natural bentonites modified with aluminum and iron (III) polyhydroxocations

The effective nanostructured sorbents based on natural bentonite modified with aluminum and iron (III) polyhydroxocations were obtained. The elemental composition of the obtained sorbents was studied. The specific surface area was determined for the studied samples. It was shown that modified sorbents based on natural bentonite were nanostructured objects. IR spectroscopy showed that modification of natural bentonite led to the changes in its structural properties.

Synthesis of Magnetic Sorbents Based on Magnetite Nanoparticles and Humic Acids and Their Application for Sorption of Phenolic Ecotoxicants

Fe3O4 nanoparticles coated with humic acids isolated from chernozem, sapropel, peat and brown coal were obtained using hydrothermal synthesis. The properties of the obtained sorbents were carried out using IR spectroscopy, SEM and TEM, whereas saturation magnetization was established using a vibration magnetometer. The maximum content of nitrogen-containing groups was found in humic acids obtained from sapropel, while the minimum amount was found in brown coal. The sorption properties of these polymers were checked among 12 different phenols.

Studying of Sorption Methylene Blue Onto Glauconite

Sorptive properties of a natural mineral glauconite towards methylene blue were studied and a composite of both substances was obtained. Antibacterial activity of the composite has been assessed against Staphylococcus aureus FDA 209P. An enriched fraction of natural glauconite was obtained by method of magnetic separation. Surface morphology of the glauconite was examined with scanning electron microscopy. The elemental composition was investigated using energy-dispersive microanalysis and roentgen fluorimetry, the texture – using Brunauer–Emmett–Teller analysis.

Preconcentration of Е110 and Е124 Food Azodyes on Magnetite Nanoparticles Modified by CTAB

Synthetic azodyes are widely used in paint, textile, plastic, and food, beverage, and leather, cosmetic, pharmaceutical and paper industries to make products more visually attractive to consumers. Therefore, they are also the components of waste waters and should be removed due to their potential risk to human health. Many techniques have been employed to eliminate dyes from waste water and do to preconcen- tration before analysis in food or beverage objects. One of the most popular and effective is magnetic solid-phase extraction (MSPE) with the use of magnetic nanoparticles (MNP).

Competitive Binding of K+ in the Presence of Na+ with Bovine Serum Albumin and Hemoglobin

Selective accumulation of monovalent cations K+, Na+, Rb+, Cs+ with albumin and hemoglobin is shown. Preferential sorption of potassium in the presence of sodium with test proteins is determined. It is shown that with increasing concentrations of sodium in the composition of aqueous solutions of the proteins, the amount of potassium bound by proteins increases.

Sorption-fluorimetric Determination of Enrofloxacin with Magnetite Nanoparticles Modified by Polyethylenimine

A technology for magnetite nanoparticles surface modification by polyethylenimine was proposed. The sizes of the nanoparticles using transmittance microscopy method were determined. The influence of pH, time of mixing, sorbent and antibiotic concentration on the enrofloxacin sorption was investigated and optimal conditions of extraction were found. Enrofloxacin sorption from plasma-modelling solution was studied and was shown that that in optimal conditions the extent of sorption is 78% and desorption from magnetite modified nanoparticles using ethanol-sodium dodecylsulfate is 95%.

ФИЗИКО-ХИМИЧЕСКИЕ СВОЙСТВА ДИСПЕРСНОГО КРЕМНЕЗЁМА-ОПОКИ

Исследована кинетика ионного обмена ионов Co2+ и Cu2+ на Na-
форме дисперсного кремнезёма-опоки. Рассчитанные значения
константы скорости адсорбции металлов на опоке и внешне- и
внутридиффузионный механизмы в зависимости от концентра-
ции исходного раствора и размера зерна сорбента показали,
что механизм лимитирующей стадии зависит от концентрации
исходного раствора и размера зерна сорбента. Найдено, что
эффективный коэффициент диффузии линейно зависит от ра-